A Selective Synthesis of the 1,3,4-Triphospholide Anion
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https://figshare.com/articles/dataset/A_Selective_Synthesis_of_the_1_3_4_Triphospholide_Anion/3256219
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资源简介:
[Mg2(μ-Cl)3(THF)6][2,5-(CtBu)2-1,3,4-P3] and
K[2,5-(CtBu)2-1,3,4-P3] are formed quantitatively from
reduction of the tricyclic-triphosphorus compound ClP3(CtBu)2 with Mg or K; the mechanistic insights gained
from these studies lead to a new and “economic” synthesis of the [2,5-(CtBu)2-1,3,4-P3]- anion from the phosphalkyne tBuC⋮P.
创建时间:
2016-05-05



