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A Ruthenated [3]Dendralene from Phenylethyne and an η3-Butadienyl–Ruthenium Complex

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Ruthenated_3_Dendralene_from_Phenylethyne_and_an_sup_3_sup_Butadienyl_Ruthenium_Complex/2502973
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The reaction of HCCPh with Ru­{η3-C­(CN)2CPhCC­(CN)2}­(PPh3)­Cp (1) affords as one product the metalated [3]­dendralene Ru­{CPhCHC­[C­(CN)2]­CPhC­(CN)2}­{NC­[Ru­(PPh3)2Cp]}­Cp (2), in which a molecule of Ru­(CN)­(PPh3)2Cp is also coordinated via the CN nitrogen to the Ru center, as shown by a single-crystal X-ray structural determination.
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2016-02-20
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