A Ruthenated [3]Dendralene from Phenylethyne and an η3-Butadienyl–Ruthenium Complex
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https://figshare.com/articles/dataset/A_Ruthenated_3_Dendralene_from_Phenylethyne_and_an_sup_3_sup_Butadienyl_Ruthenium_Complex/2502973
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The reaction of HCCPh with Ru{η3-C(CN)2CPhCC(CN)2}(PPh3)Cp (1) affords as one product the metalated [3]dendralene Ru{CPhCHC[C(CN)2]CPhC(CN)2}{NC[Ru(PPh3)2Cp]}Cp (2), in which a molecule of Ru(CN)(PPh3)2Cp is also coordinated via the CN nitrogen to the Ru center, as shown by a single-crystal X-ray structural determination.
创建时间:
2016-02-20



