Rhodium-Catalyzed Cycloadditions between 3‑Diazoindolin-2-imines and 1,3-Dienes
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https://figshare.com/articles/dataset/Rhodium-Catalyzed_Cycloadditions_between_3_Diazoindolin-2-imines_and_1_3-Dienes/4800784
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资源简介：
Azepino[2,3-b]indoles
were regioselectively prepared
through rhodium-catalyzed formal aza-[4 + 3] cycloaddition between
3-diazoindolin-2-imines and 1,3-dienes in moderate to good yields.
Using 2-[(trimethylsilyl)oxy]-1,3-butadiene as the diene component,
azepino[2,3-b]indol-4(1H)-ones were
constructed. Furthermore, the reactions of cyclic dienes, such as
1,3-cyclohexadiene and 1,3-cyclopentadiene, furnished the corresponding
[3 + 2] cycloaddition products.
创建时间：
2017-03-29
