Multifunctionalized 3-Hydroxypyrroles in a Three-Step, One-Pot Cascade Process from Methyl 3-TBSO-2-diazo-3-butenoate and Nitrones
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Multifunctionalized_3_Hydroxypyrroles_in_a_Three_Step_One_Pot_Cascade_Process_from_Methyl_3_TBSO_2_diazo_3_butenoate_and_Nitrones/2582443
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资源简介：
The synthesis of N-aryl-2-carboxyl-3-hydroxy-5-arylpyrroles has been achieved in high yield by the combination of a TBSO-substituted vinyldiazoacetate and nitrones in a one-pot cascade process involving copper-catalyzed Mannich addition, dirhodium-catalyzed dinitrogen extrusion and N-OTBS insertion, and acid-promoted aromatization (elimination).
创建时间：
2016-02-22
