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Design and Synthesis of New Macrocyclic Cyclophanes Using 1,3-Dioxane Units as Bridges: A Molecular “Rocking Chair”

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https://figshare.com/articles/dataset/Design_and_Synthesis_of_New_Macrocyclic_Cyclophanes_Using_1_3_Dioxane_Units_as_Bridges_A_Molecular_Rocking_Chair_/3349279
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资源简介:
The design, synthesis and structural analysis of architecturally new cyclophanes (monomers, dimers, and trimers) are reported. Variable temperature NMR experiments reveal a regular, tandem dynamic in the cyclophane 2a that enables its description as a “molecular rocking chair”. The NMR and X-ray structure investigations show important intra- and intermolecular aromatic π-stacking interactions.
创建时间:
2004-02-20
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