N‑Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls
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https://figshare.com/articles/dataset/N_Coordinated_Tin_II_Trifluoromethanesulfonates_and_Their_Reactions_with_Transition_Metal_Carbonyls/2148322
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资源简介：
The syntheses of the compounds [L1SnCl][M(CO)5(SnCl3)] (3, M = W; 4, M = Cr), [L1SnCl]OTf
(5), [L1SnCl][W(CO)5(SnCl2OTf)] (6), [L1SnOTf][OTf] (7), and [L2Sn(OTf)2] (8) with L1 = {2,6-[(CH3)CN(C6H3-2,6-iPr2)2]C5H3N} (DIMPY) and L2 = {2-[(CH3)CN(C6H3-2,6-iPr2)]-6-(CH3O)}C5H3N) is reported. The compounds
were characterized by elemental analyses, 1H, 13C, 19F, and 119Sn NMR spectroscopy, electrospray
ionization mass spectrometry, and single-crystal X-ray diffraction
analyses (3·1.5C7H8, 5·CH2Cl2, 7·C7H8, 8). For compounds 7 and 8, the experimental work is accompanied by density
functional theory calculations.
创建时间：
2016-02-13
