Coordination of Phosphinoboranes R2PB(C6F5)2 to Platinum: An Alkene-Type Behavior
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https://figshare.com/articles/dataset/Coordination_of_Phosphinoboranes_R_sub_2_sub_PB_C_sub_6_sub_F_sub_5_sub_sub_2_sub_to_Platinum_An_Alkene_Type_Behavior/2530258
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The paucity of boron-containing heteroalkene complexes prompted us to explore the coordination of phosphinoboranes. The complexes {[R2PB(C6F5)2]Pt(PPh3)2} (R = Cy, t-Bu) were obtained by ethylene displacement. Spectroscopic and crystallographic data indicated symmetric side-on coordination of the phosphinoborane to Pt. Thorough analysis of the bonding situation by computational means revealed important similarities but also significant differences between the phosphinoborane and ethylene complexes.
创建时间：
2016-02-21
