Syntheses and Structures of Phenyl-C<sub>81</sub>-Butyric Acid Methyl Esters (PCBMs) from M<sub>3</sub>N@C<sub>80</sub>
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Two new 6,6-open phenyl-C81-butyric acid methyl ester metallofulleroids, M3N@C80PCBM (M = Sc, Y), were synthesized by diazoalkane addition reactions and fully characterized. The results demonstrate that the reactive sites are the same for M3N@C80 (M = Sc, Y) but dramatically different from that of C60.
创建时间：
2009-04-16
