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Dehydrative Thiolation of Allenols: Indium vs Gold Catalysis

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NIAID Data Ecosystem2026-03-07 收录
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Intermolecular additions of thiols to allenols via formal SN2′ selectivity to produce functionalized dienes are described. Although this dehydrative reaction was initially developed using gold­(I) catalysis, indium­(III) proves to be a far superior catalyst in terms of selectivity and substrate scope.

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2015-02-06
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