[Ni(phen)<sub>3</sub>]<sub>2</sub>Sb<sub>18</sub>S<sub>29</sub>: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)<sub>3</sub>] Complexes
收藏NIAID Data Ecosystem2026-03-09 收录
数据链接：
官方服务：
资源简介：
A novel thioantimonate(III), namely, [Ni(phen)3]2Sb18S29 (1; phen = 1,10-phenanthroline), has been solvothermally synthesized. Its structure features a three-dimensional framework with the largest channels in thioantimonates. The chiral [Ni(phen)3]2+ cations and the Sb:S ratio (1:1.611) in 1 are unique among those in the reported thioantimonates. The thermal stability, optical properties, and electric conductivity as well as the theoretical band structure and density of state of 1 have also been studied.
创建时间：
2016-02-21
