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Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Osmium_and_Ruthenium_Catalysts_for_Dehydrogenation_of_Alcohols/2632332
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A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C2H4PiPr2)2] and OsH2(CO)[HN(C2H4PiPr2)2] possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.
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2016-02-23
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