Partially and Fully Reversible Solvation-Controlled Borylene Swapping and Metal-Only Lewis Pair Formation
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https://figshare.com/articles/dataset/Partially_and_Fully_Reversible_Solvation_Controlled_Borylene_Swapping_and_Metal_Only_Lewis_Pair_Formation/2274748
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资源简介：
New borylene-containing metal-only
Lewis pairs based on group 6
metals and ruthenium are prepared by a partially reversible borylene
transfer from group 6 borylene complexes [M{BN(SiMe3)2}(CO)5] (M = Mo, W). The complexes
contain strong Ru → Mo/W dative interactions. As in a previous
report on related compounds, redissolving these complexes resulted
in reversion back to the precursors, enabled by a sacrificial CO donor.
It was observed that this reversion process becomes less selective
as the group 6 metal becomes heavier, leading to greater amounts of
unidentified byproducts as the group is descended.
创建时间：
2016-02-17
