Crystal and magnetic structures of YRUO3
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Perovskites like SrRuO3 based on Ru(IV) are common, but Ru(III) oxides are rare although Ru3+ is of great interest as a low spin d5 cation like Ir4+ where strong spin-orbit...
以四价钌(Ru(IV))为基础的锶钌氧化物(SrRuO₃)这类钙钛矿(Perovskites)较为常见,但三价钌(Ru(III))氧化物则相对稀缺。尽管三价钌离子(Ru³+)作为与四价铱离子(Ir⁴+)为为类似的低自旋d5阳离子(low spin d5 cation),因其强自旋轨道(spin-orbit)效应而广受关注……



