Host–Guest Complexes of Pentiptycene Receptors Display Edge-to-Face Interaction
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https://figshare.com/articles/dataset/Host_Guest_Complexes_of_Pentiptycene_Receptors_Display_Edge_to_Face_Interaction/2463520
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The pentiptycene receptors form edge-to-face complexes with a variety of aromatic guests including nitroaromatics. X-ray diffractometry revealed that compounds 1, 2, and 3 form host–guest assemblies with a thienyl fragment (from a neightboring molecule of 1), benzene and nitrobenzene, respectively. X-ray studies of the three crystal structures reported here strongly suggest the edge-to-face to be a predominant binding mode between the aromatic guests and electron-rich faces of the pentiptycene aromatic cavity.
创建时间：
2016-02-20
