Formal Total Synthesis of (±)-Cephalotaxine and Congeners via Aryne Insertion Reaction
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https://figshare.com/articles/dataset/Formal_Total_Synthesis_of_Cephalotaxine_and_Congeners_via_Aryne_Insertion_Reaction/3172378
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The formal total synthesis of pentacyclic core alkaloid, (±)-cephalotaxine is achieved in nine steps from known 2-allylpyrrolidine-2-carboxaldehyde using aryne insertion reaction as a key step in 10% overall yield. The developed novel strategy enabled easy access to cephalotaxine congeners.
创建时间：
2016-05-02
