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A Highly Efficient Luminescent Pt2Tl2 Chain with a Short TlI–TlI Interaction

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Highly_Efficient_Luminescent_Pt_sub_2_sub_Tl_sub_2_sub_Chain_with_a_Short_Tl_sup_I_sup_Tl_sup_I_sup_Interaction/2369620
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The preparation of an unsupported tetranuclear cluster with a linear Pt0–TlI–TlI–Pt0 metal chain is described. The complex shows strong red emission in the solid state, having a quantum yield of 73%. Density functional theory (DFT) and time-dependent DFT calculations show that red emission originated from a platinum to thallium–thallium charge-transfer excited state.
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2016-02-18
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