Co(II)-MOF: A Highly Efficient Organic Oxidation Catalyst with Open Metal Sites

A porous Co­(II)-MOF
(1) was synthesized by the combination
of a bent imidazole-bridged ligand and p-phthalic
acid (PTA) with Co­(OAc)2 under solvothermal conditions.
This Co­(II)-MOF (1) is able to undergo a reversible MeOH
substitution reaction on the Co­(II) center via a single-crystal-to-single-crystal
process. The desolvated Co­(II)-MOF (2) with the open
Co­(II) sites is very stable (up to 350 °C). Furthermore, 2 is a highly active heterogeneous catalyst for various organic
substrates oxidation in the presence of tert-butyl
hydroperoxide (TBHP) under milder conditions. The importance of open
Co­(II) sites in 2 for the organic substrates oxidation
is directly evidenced by the single-crystal X-ray diffraction.