Buckled Layers in K<sub>0.66</sub>Mn<sub>2</sub>O<sub>4</sub>·0.28H<sub>2</sub>O and K<sub>0.99</sub>Mn<sub>3</sub>O<sub>6</sub>·1.25H<sub>2</sub>O Synthesized at High Pressure: Implication for the Mechanism of Layer-to-Tunnel Transformation in Manganese Oxides
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数据链接：
https://figshare.com/articles/dataset/Buckled_Layers_in_K_sub_0_66_sub_Mn_sub_2_sub_O_sub_4_sub_0_28H_sub_2_sub_O_and_K_sub_0_99_sub_Mn_sub_3_sub_O_sub_6_sub_1_25H_sub_2_sub_O_Synthesized_at_High_Pressure_Implication_for_the_Mechanism_of_Layer_to_Tunnel_Transformation_in_Manganese_Oxides/2680813数据链接链接失效反馈
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资源简介：
A 2 × 2 layer-buckled manganese oxide, K0.66Mn2O4·0.28H2O (I), has been synthesized under high pressure and retained at ambient pressure; it is metastable and will finally transform to a 2 × 1 layer-buckled K0.99Mn3O6·1.25H2O (II) in 1 year. Both crystal structures were determined by single-crystal X-ray diffraction. On the basis of these buckled layers, which are a result of ordering of Mn3+/Mn4+ in separate rows and cooperative Jahn−Teller distortion of Mn3+O6 octahedra, a mechanism of structure transformation from birnessite to tunnel structures was proposed.
创建时间：
2011-03-21
