Unravelling the structure of Zn promoter in Cu/ZnO-based model catalysts for CO2-to-methanol by 1s2p-RIXS under high pressure reaction condi
收藏ESRF Portal2028-01-01 更新2026-04-23 收录
下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-2008418956
下载链接
链接失效反馈官方服务：
资源简介：
The nature and catalytic role of zinc in Cu/ZnO-based CO2-to-methanol catalysts have long been subject of debate. Specifically, it is speculated whether tetrahedral [ZnO4] or octahedral [ZnO6] constitutes the active sites, and how the degree of reduction of Zn at the ZnOx-Cu interface affects the activity. In both cases, X-ray absorption spectroscopy was used for in situ and operando catalyst characterization, but differentiation of the Zn species is limited.
Our aim is to perform 1s2p-RIXS, measured at the off-diagonal of the Zn Kα1,2 emission lines, which contains well-distinguishable spectral fingerprints of metallic phases, as well as tetrahedrally and octahedrally coordinated Zn. The proposed beamtime is expected to give qualitative and quantitative analysis of the Zn species in a model catalyst under reaction conditions.
提供机构：
Universitaet Karlsruhe, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131 Karlsruhe, Germany; Karlsruhe Institute of Technology, Department of Chemistry and Biology, Institut fuer Technische Chemie und, Polymerchemie Kaiserstr. 12, 76131 Karlsruhe, Germany; Christian Albrechts Universitaet Kiel, Institut fuer Anorganische Chemie, Max-Eyth-Strasse 2, 24118, Kiel, DE; Karlsruhe Institute of Technology, ITCP, Engesserstr. 20, Campus South, 76131 Karlsruhe, Germany
创建时间：
2028-01-01
