Alkene Dioxygenation with Malonoyl Peroxides: Synthesis of γ‑Lactones, Isobenzofuranones, and Tetrahydrofurans
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https://figshare.com/articles/dataset/Alkene_Dioxygenation_with_Malonoyl_Peroxides_Synthesis_of_Lactones_Isobenzofuranones_and_Tetrahydrofurans/3443174
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资源简介：
Treatment
of homoallylic alcohols or carboxylic acids with malonoyl
peroxide 1 provides a stereoselective method for the
preparation of tetrahydrofurans, γ-lactones, and isobenzofuranones
in 44–82% yield and up to 27:1 trans selectivity.
Application of this simple and effective heterocyclization in the
synthesis of the antidepressant citalopram is also described.
创建时间：
2016-06-27
