Nazarov Type Cyclization on an Osmium−Dienylcarbene Complex

NIAID Data Ecosystem2026-03-06 收录

Nazarov环化反应

金属有机化学

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https://figshare.com/articles/dataset/Nazarov_Type_Cyclization_on_an_Osmium_Dienylcarbene_Complex/2877904 数据链接链接失效反馈

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Nazarov Type Cyclization on an Osmium−Dienylcarbene Complex

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2016-02-26

Insertion of Isonitriles into the M–C Bonds of Group 4 Dialkyl Complexes

金属有机化学

异腈插入反应机理

The 2,3-dimethylbutadiene complexes of Group 4 metals with constrained geometry (cg) ligands have been prepared and found to adopt a supine orientation with σ2,π bonding. Treatment of cgTi(2,3-dimet

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Synthesis, Structure, and Bridge-Terminal Exchange Kinetics of Pyrazolate-Bridged Digallium and Diindium Complexes Containing Bridging Phenyl Groups

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Treatment of triphenylgallium with 3,5-dimethylpyrazole, 3,5-diphenylpyrazole, or 3,5-di-tert-butylpyrazole in a 2:1 stoichiometry afforded the phenyl-bridged complexes (C6H5)2Ga(μ-Me2pz)(μ-C6H5)Ga(C6

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Activation of Molecular Oxygen by a Molybdenum(IV) Imido Compound

金属有机化学

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Activation of molecular dioxygen at a molybdenum(IV) imido compound led to the isolation and full characterization of a remarkably stable transition-metal imidoperoxido complex.

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Structural and Spectroscopic Studies of the PCP-Bridged Heavy Chalcogen-Centered Monoanions [HC(PPh 2 E)(PPh 2 )] − (E = Se, Te) and [HC(PR 2 E) 2 ] − (E = Se, Te, R = Ph; E = Se, R = i Pr): Homoleptic Group 12 Complexes and O

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Selenium- and tellurium-containing bis(diphenylphosphinoyl)methane monoanions were prepared by oxidation of the anion [HC(PPh2)2]− with elemental chalcogens. The selenium-containing isopropyl derivati

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Formation of Acene-Based Polymers: Mechanistic Computational Study

并苯聚合物形成机理

金属有机化学

Understanding the mechanism of linear acene decomposition and its reactivity is a prerequisite for controlling the stability of acenes and their future applications. Previously, we suggested that long

Figshare2016-02-18 更新30

Nazarov Type Cyclization on an Osmium−Dienylcarbene Complex

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