Total Synthesis of the Illicium-Derived Sesquineolignan Simonsol C
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https://figshare.com/articles/dataset/Total_Synthesis_of_the_i_Illicium_i_-Derived_Sesquineolignan_Simonsol_C/3481844
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The racemic form of the title natural product 1 has been synthesized by engaging, as a key step, the iodoarene-tethered cyclohexene 22 in an intramolecular Heck reaction to give compound 23. This angularly substituted tetrahydrodibenzo[b,d]furan was elaborated over a further five steps into target (±)-1.
创建时间:
2016-08-01



