Stereospecific Synthesis of Dienones via a Torquoselective Retro-Nazarov Reaction
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https://figshare.com/articles/dataset/Stereospecific_Synthesis_of_Dienones_via_a_Torquoselective_Retro_Nazarov_Reaction/3289120
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资源简介:
Enol ethers are cleaved via a three-step sequence involving cycloaddition with dichloroketene, ring expansion with diazomethane, and a
base-mediated retro-Nazarov reaction. The latter conrotatory process proceeds torquoselectively and stereospecifically in accord with theoretical
predictions.
创建时间:
2016-05-06



