Cluster Organic Frameworks Constructed from Heterometallic Supertetrahedral Cluster Secondary Building Units
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https://figshare.com/articles/dataset/Cluster_Organic_Frameworks_Constructed_from_Heterometallic_Supertetrahedral_Cluster_Secondary_Building_Units/4789465
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资源简介：
The
two novel cluster organic frameworks based on heterometallic supertetrahedral
cluster secondary building units (SBUs) [Cd4Cu6(L)4(Ac)7(H2O)4](Ac)·7H2O (1) and [Mn4Cu6(L)4(Ac)4.5(H2O)9]CuCN(Ac)3.5·H2O (2), where H3L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol and Ac = CH3COO–, have been prepared under solvothermal
conditions. 1 and 2 are the first cases
of cluster organic frameworks containing Cd-Cu/Mn-Cu heterometallic
supertetrahedral cluster SBUs. Furthermore, 1 and 2 show an integration of magnetic properties and adsorption
properties from both the heterometallic cluster secondary building
units and the framework in a porous material.
创建时间：
2017-03-27
