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A Large Protonated Water Cluster H<sup>+</sup>(H<sub>2</sub>O)<sub>27</sub> in a 3D Metal−Organic Framework

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NIAID Data Ecosystem2026-03-06 收录
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A large protonated water cluster, H+(H2O)27, has been trapped and stabilized within the well-modulated cavity of a 3D metal−organic framework formed by cobalt(II) and 4,4‘-bipyridine-N,N‘-dioxide with a globular Keggin structure [PW12O4]3- anion as template. The structurally characterized protonated water cluster might comprise a (H2O)26 shell with Oh symmetry and a monowater core within the center which is suggested to be a hydronium ion with the Eigen model.

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2016-02-29
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