Cu(I)-Catalyzed Tandem Reaction of Carbene Coupling and Horner–Wadsworth–Emmons Type Olefination: Access toward Enynes
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https://figshare.com/articles/dataset/Cu_I_Catalyzed_Tandem_Reaction_of_Carbene_Coupling_and_Horner_Wadsworth_Emmons_Type_Olefination_Access_toward_Enynes/3201343
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A novel strategy to synthesize 1,3-enynes has been successfully developed based on Cu(I)-catalyzed cross-coupling of α-diazo phosphonates and alkynes with a subsequent Horner–Wadsworth–Emmons (HWE) type reaction. This method provides straightforward access to conjugated enynes with high efficiency, good stereoselectivity and excellent functional group compatibility. Copper(I) carbene migratory insertion plays a crucial role in this transformation.
创建时间：
2016-05-02
