Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity
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https://figshare.com/articles/dataset/Organobismuth_III_and_Dibismuthine_Complexes_Bearing_N_N_Disubstituted_1_8_Diaminonaphthalene_Ligand_Synthesis_Structure_and_Reactivity/2484241
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资源简介：
The organobismuth(III) and dibismuthine complexes bearing
N,N′-disubstituted
1,8-diaminonaphthalene ligand were prepared. The reaction of LBiNMe2 (1) [L = 1,8-(NSiMe3)2C10H6] with ClSiMe3 results in the
elimination of Me3SiNMe2, while PhCCH, Cp*H,
and PhOH proceed via HNMe2 elimination and provide the
complexes of LBiCl (2), LBiCCPh (3), LBiCp*(4), and LBiOPh (5), respectively. Reaction of 1 with AlMe3 in n-hexane yields
LBiMe (6). Compound 1 reacts with diisopropylcarbodiimide
and phenyl isocyanate under insertion at the Bi–NMe2 bond to give the addition products LBi(N-iPr)2CNMe2 (7) and LBiN(Ph)C(O)NMe2 (8). The reactions of 1 with sulfur
and PhSiH3 result in
the formation of LBi–S–BiL (9) and LBi–BiL
(10), respectively. Compounds 2–10 were characterized by elemental analysis, 1H, 13C, and 29Si NMR spectroscopy, and X-ray crystallographic
studies.
创建时间：
2012-09-24
