The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides
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https://figshare.com/articles/dataset/The_Hexachlorocerate_III_Anion_A_Potent_Benchtop_Stable_and_Readily_Available_Ultraviolet_A_Photosensitizer_for_Aryl_Chlorides/4306802
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The hexachlorocerate(III) anion, [CeIIICl6]3–, was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction potential of −3.45 V versus Cp2Fe0/+. Despite a short lifetime of 22.1(1) ns, the anion exhibited a photoluminescence quantum yield of 0.61(4) and fast quenching kinetics toward organohalogens allowing for its application in the photocatalytic reduction of aryl chloride substrates.
创建时间：
2018-01-01
