Why Are (NN<sub>2</sub>)Ni Pincer Complexes Active for Alkyl−Alkyl Coupling: β-H Elimination Is Kinetically Accessible but Thermodynamically Uphill
收藏NIAID Data Ecosystem2026-03-06 收录
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Isomerization and olefin exchange experiments show that β-H elimination is kinetically viable but thermodynamically unfavorable in [(MeNN2)Ni-alkyl] complexes. The intermediacy of Ni-hydride species was corroborated by a trapping experiment. The alkyl complex [(MeNN2)Ni-propyl] catalyzes olefin isomerization.
创建时间：
2010-09-13
