Asymmetric Transamination of α‑Keto Acids Catalyzed by Chiral Pyridoxamines
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https://figshare.com/articles/dataset/Asymmetric_Transamination_of_Keto_Acids_Catalyzed_by_Chiral_Pyridoxamines/3493388
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资源简介：
A new type of novel
chiral pyridoxamines 3a–g containing
a side chain has been developed. The pyridoxamines
displayed catalytic activity and promising enantioselectivity in biomimetic
asymmetric transamination of α-keto acids, to give various α-amino
acids in 47–90% yields with up to 87% ee’s under very
mild conditions. An interesting effect of the side chain on enantioselectivity
was observed in the reaction.
创建时间：
2016-08-01
