Auto-Tandem Palladium Catalysis: From Isoxazole to 2‑Azafluorenone
收藏Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Auto_Tandem_Palladium_Catalysis_From_Isoxazole_to_2_Azafluorenone/2106874
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An auto-tandem palladium catalysis from halogen-substituted isoxazoles and Michael acceptors is described. It involves two mechanistically distinct palladium-catalyzed reactions, a Heck reaction and a rearrangement, leading to 2-azafluorenones. It is the first example of palladium-catalyzed ring opening of isoxazoles and rearrangement of the β-imino ketone ring-opening product.
创建时间：
2016-02-12
