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Synthesis and Structures of Zigzag Shaped [12]Cyclo‑p‑phenylene Composed of Dinaphthofuran Units and Biphenyl Units

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Figshare2017-07-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Structures_of_Zigzag_Shaped_12_Cyclo_i_p_i_phenylene_Composed_of_Dinaphthofuran_Units_and_Biphenyl_Units/5229631
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A [12]­Cyclo-p-phenylene 9 composed of dinaphthofuran units and biphenyl units was synthesized through reductive elimination of the corresponding trinuclear complex by applying Yamago’s method. The X-ray crystallographic analyses of 9 revealed that it adopts a zigzag conformation in the solid state. The UV–vis and fluorescence measurements of compound 9 indicated that it also preferentially took a zigzag conformation in the solution state.
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2017-07-20
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