Total Synthesis of the Sesquiterpenoid Periconianone A Based on a Postulated Biogenesis
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https://figshare.com/articles/dataset/Total_Synthesis_of_the_Sesquiterpenoid_Periconianone_A_Based_on_a_Postulated_Biogenesis/5563024
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资源简介：
The first enantioselective total
synthesis of the complex tricarbocyclic
sesquiterpenoid periconianone A based on a postulated biogenesis is
reported. Key elements of the synthetic route include the use of an
isopropenyl group as a removable directing group for stereoselective
synthesis, a sequence featuring a Rh-mediated O–H insertion/[3,3]-sigmatropic
rearrangement and subsequent α-ketol rearrangement, and a late
stage aldol reaction to furnish the complex cage-like framework.
创建时间：
2017-11-02
