Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds
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https://figshare.com/articles/dataset/Phosphorus_I_Iodide_A_Versatile_Metathesis_Reagent_for_the_Synthesis_of_Low_Oxidation_State_Phosphorus_Compounds/3063778
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资源简介：
An improved method for the synthesis of cyclic low oxidation state P cations is presented. The only byproducts of
the reaction of phosphorus triiodide with chelating phosphines are readily removed, resulting in an easily accessible
PI reagent with an anion that can be readily replaced through salt metathesis chemistry. These PI salts are surprisingly
stable, even in O2 and moisture, and the origin of this unusual stability is elucidated using density functional theory
calculations.
创建时间：
2016-02-29
