Synthesis and Dynamic Behavior of an Anthyridine-Ligated Ruthenium Complex
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https://figshare.com/articles/dataset/Synthesis_and_Dynamic_Behavior_of_an_Anthyridine_Ligated_Ruthenium_Complex/2243452
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资源简介：
A ruthenium complex containing a
1,9,10-anthyridine derivative, [Ru(L)(bpy)2](PF6)2 ([1](PF6)2; L =
1,13,14-triazadibenz[a,j]anthracene,
bpy = 2,2′-bipyridyl), was synthesized. X-ray crystal structural
analysis of [1](PF6)2 showed that
L is coordinated to the Ru center as a bidentate ligand. When [1](PF6)2 was dissolved in acetonitrile,
a new complex incorporating one acetonitrile molecule, [Ru(L)(CH3CN)(bpy)2](PF6)2 ([2](PF6)2), was formed. X-ray crystallographic
data revealed that, in [2](PF6)2, L is coordinated to the Ru center in a monodentate fashion. The
coordinated L in [2](PF6)2 shows
a unique haptotropic rearrangement in an acetonitrile solution.
创建时间：
2014-10-20
