Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal–Organic Frameworks
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https://figshare.com/articles/dataset/Ligand-Directed_Reticular_Synthesis_of_Catalytically_Active_Missing_Zirconium-Based_Metal_Organic_Frameworks/9104732
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资源简介：
Zirconium-based metal–organic
frameworks (Zr-MOFs) based
on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs
based on the highly connected 6,12-connected alb net,
however, remain absent on account of synthetic challenges. Herein
we report the ligand-directed reticular syntheses and isoreticular
expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and
6-connected trigonal-prismatic linkers, i.e., microporous NU-1600,
mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit
remarkable activities toward the destruction of a nerve agent (soman)
and a nerve agent simulant (DMNP).
创建时间：
2019-07-25
