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First Structural Characterization of Neutral, Base-Stabilized Group 15-Pentaazides: Single Crystal X-ray Structures of dmap-As(N3)5 and dmap-Sb(N3)5

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/First_Structural_Characterization_of_Neutral_Base_Stabilized_Group_15_Pentaazides_Single_Crystal_X_ray_Structures_of_dmap_As_N_sub_3_sub_sub_5_sub_and_dmap_Sb_N_sub_3_sub_sub_5_sub_/2521201
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Two neutral group 15-pentaazides dmap-As­(N3)5 (1) and dmap-Sb­(N3)5 (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides.
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2016-02-20
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