Acid-Induced Molecular Folding and Unfolding of <i>N</i>-Methyl Aromatic Amide Bearing 2,6-Disubstituted Pyridines
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The structural features and conformational conversion of the N-methyl pyridyl amide oligomer bearing 2,6-disubstituted pyridines were investigated. 1H NMR and X-ray crystallography revealed that the environment-responsive type of conformational control can be performed. The amide bond switching together with intramolecular hydrogen-bonding effects caused dynamic protonation-associated conformational conversion from layered to spiral and then flat.
创建时间：
2007-02-21
