Synthesis and Catalytic Activity of Water-Soluble Ruthenium(II) Complexes Bearing a Naphthyridine–Carboxylate Ligand
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https://figshare.com/articles/dataset/Synthesis_and_Catalytic_Activity_of_Water_Soluble_Ruthenium_II_Complexes_Bearing_a_Naphthyridine_Carboxylate_Ligand/2285008
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资源简介：
The synthesis of water-soluble (η6-arene)ruthenium(II)
complexes based on pyrazolyl–naphthyridine ligands modified
with a carboxylate group is reported. The complexes are easily accessible
in good yields via complexation of [(arene)RuCl2]2 with 7-pyrazolyl-1,8-naphthyridine-2-carboxylic acid (1). All complexes have been characterized by spectroscopic and elemental
analyses. The complexes {[Ru(η6-arene)(N,N′-1)Cl]Cl} (arene = benzene
(5), p-cymene (6)) were
further confirmed by X-ray diffraction studies. These complexes are
soluble in water (ca. 10 mg/mL) and are catalytically active in hydrogen-transfer
reduction of carbonyl compounds in aqueous medium with the use of
HCOOH/HCOONa as the hydrogen source.
创建时间：
2014-06-09
