Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Carbonyl_Complexes_of_Platinum_0_Synthesis_and_Structure_of_Cy_sub_3_sub_P_sub_2_sub_Pt_CO_and_Cy_sub_3_sub_P_sub_2_sub_Pt_CO_sub_2_sub_/2686153
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The platinum(0) monocarbonyl complex, [(Cy3P)2Pt(CO)], was synthesized by reaction of [(Cy3P)2Pt] with [(η5-C5Me5)Ir(CO)2] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine ligands. Its corresponding dicarbonyl complex [(Cy3P)2Pt(CO)2] was synthesized by treatment of [(Cy3P)2Pt] with CO at −40 °C and confirmed by X-ray structure analysis.
创建时间：
2016-02-23
