A Comparison of Isomers: <i>trans</i>- and <i>cis</i>-Dicyanobis(<i>para</i>-ethylisocyanobenzene)Platinum
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We report the synthesis and characterization of trans-Pt(p-CN−C6H4−C2H5)2(CN)2 and compare the properties to the previously reported cis isomer, cis-Pt(p-CN−C6H4−C2H5)2(CN)2. These geometric isomers exhibit textbook differences in spectroscopic and vapochromic properties, especially in the solid-state.
创建时间:
2007-12-03



