Inhibition and Stabilization: Cucurbituril Induced Distinct Effects on the Schiff Base Reaction
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https://figshare.com/articles/dataset/Inhibition_and_Stabilization_Cucurbituril_Induced_Distinct_Effects_on_the_Schiff_Base_Reaction/4728538
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资源简介：
The
different effects of cucurbit[7]uril (CB[7]) on the Schiff
base reactions in aqueous solution were explored by 1H
NMR spectroscopy and single X-ray crystallography. With CB[7], the
condensation reaction of aldehyde and primary amine is dramatically
inhibited. In contrast, the presence of CB[7] does tremendously stabilize
iminium cation in water through ion–dipole interactions. A
single crystal structure of the complex of iminium ion 7 with CB[7] grown in water is reported.
创建时间：
2017-03-06
