Design of fast redox-controlled self-immolative selenium-based cysteine surrogates
收藏DataCite Commons2026-01-28 更新2026-04-25 收录
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https://datadryad.org/dataset/doi:10.5061/dryad.2bvq83c2q
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资源简介：
The self-immolation of N-selenoethyl cysteine derivatives into cysteine
exhibits a strong Thorpe-Ingold effect. Notably, the gem-dimethyl
substitution alpha to the selenium atom achieved rate accelerations up to
252-fold, enabling Cys unmasking through C-N bond cleavage within minutes.
These investigations offer valuable insights into the mechanism of
selenoethyl arm breakdown and new redox-sensitive Cys surrogates.
提供机构：
Dryad
创建时间：
2025-06-17
