Metal−Metal Bond Opening Toward Main Group−Transition Element Rings
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https://figshare.com/articles/dataset/Metal_Metal_Bond_Opening_Toward_Main_Group_Transition_Element_Rings/3767073
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资源简介：
The reaction of the cluster Os6(μ4-Sb)(μ-H)2(μ-SbPh2)(μ3,η2-C6H4)(μ3,η4-C12H8)(CO)15, 1, with excess
tBuNC resulted in ring expansion via metal−metal bond
cleavage to afford the novel compounds Os6(μ4-Sb)(μ-H)(μ-SbPh2)(C6H5)(μ3,η4-C12H8)(CO)14(CNtBu)4, 2, and Os6(μ4-Sb)(μ-H)(μ-SbPh2)(C6H5)(μ3,η4-C12H8)(CO)15(CNtBu)3, 3, both of which contain five-membered Os3Sb2
rings.
创建时间：
2016-08-26
