Synthesis and Characterization of Two New Mn(II) Coordination Polymers Containing Different Metal-Carboxylate Chain Motifs
收藏Taylor & Francis Group2016-01-19 更新2026-04-16 收录
下载链接：
https://tandf.figshare.com/articles/dataset/Synthesis_and_Characterization_of_Two_New_Mn_II_Coordination_Polymers_Containing_Different_Metal_Carboxylate_Chain_Motifs/1250962/1
下载链接
链接失效反馈官方服务：
资源简介：
Two Mn(II) coordination polymers, formulated as [Mn(Hhtpa)<sub>2</sub>(bpa)<sub>2</sub>(H<sub>2</sub>O)]<sub>n</sub><b>(1)</b> and {[Mn(htpa)(H<sub>2</sub>O)]·H<sub>2</sub>O}<sub>n</sub><b>(2)</b> (htpa = 4-carboxyphenylacetate, bpa = 1,2-di(4-pyridyl)-ethane), have been synthesized by the hydrothermal reaction and characterized by single crystal X-ray diffraction, elemental analysis, IR and TGA. The structures of both compounds are based on different Mn(II)-carboxylate chain motifs. Complex <b>1</b> is a one-dimensional coordination polymer featuring <i>μ</i><sub>2</sub>-carboxyl bridged MnO<sub>4</sub>N<sub>2</sub> octahedra. Complex <b>2</b> contains Mn-O inorganic chains, featuring <i>μ</i><sub>2</sub>-O bridged MnO<sub>6</sub> octahedra, which are interconnected further by interchain htpa ligands to form a two-dimensional coordination polymer.
提供机构：
Guang-Zhen Liu
创建时间：
2015-01-06
