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Nuclearity Control of a Trisaloph Zinc Cluster Complex Dependent on Minute Structural Differences in the Bridging Anions

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Nuclearity_Control_of_a_Trisaloph_Zinc_Cluster_Complex_Dependent_on_Minute_Structural_Differences_in_the_Bridging_Anions/2640469
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The Zn6 cluster complex 2 of the trisaloph ligand was synthesized using EtCO2– anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn7 to Zn6.
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2016-02-23
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