Palladium-Catalyzed Dehydrogenative β′-Functionalization of β-Keto Esters with Indoles at Room Temperature
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Dehydrogenative_Functionalization_of_Keto_Esters_with_Indoles_at_Room_Temperature/2535124
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资源简介:
The dehydrogenative β′-functionalization
of α-substituted
β-keto esters with indoles proceeds with high regioselectivities
(C3-selective for the indole partner and β′-selective
for the β-keto ester) and good yields under mild palladium catalysis
at room temperature with a variety of oxidants. Two possible mechanisms
involving either late or early involvement of indole are presented.
创建时间:
2016-02-21



