Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo
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https://figshare.com/articles/dataset/Facile_Nitrite_Reduction_in_a_Non_heme_Iron_System_Formation_of_an_Iron_III_Oxo/2224525
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资源简介：
Reaction of tetrabutylammonium nitrite
with [N(afaCy)3Fe(OTf)](OTf) cleanly resulted
in the formation of an
iron(III)-oxo species, [N(afaCy)3Fe(O)](OTf),
and NO(g). Formation of NO(g) as a byproduct was confirmed by reaction
of the iron(II) starting material with half an equivalent of nitrite,
resulting in a mixture of two products, the iron-oxo and an iron-NO
species, [N(afaCy)3Fe(NO)](OTf)2.
Formation of the latter was confirmed through independent synthesis.
The results of this study provide insight into the role of hydrogen
bonding in the mechanism of nitrite reduction and the binding mode
of nitrite in biological heme systems.
创建时间：
2016-02-16
