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Self-Assembled Bidentate Ligands for Ruthenium-Catalyzed Hydration of Nitriles

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https://figshare.com/articles/dataset/Self-Assembled_Bidentate_Ligands_for_Ruthenium-Catalyzed_Hydration_of_Nitriles/12079401
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资源简介:
Novel bis(acetylacetonato)ruthenium(II) complexes bearing the 6-diphenylphosphino-N-pivaloyl-2-aminopyridine and 3-diphenylphosphinoisoquinolone ligands were synthesized. Molecular structures of these complexes were studied in solution and also in the solid state, and unusual hydrogen-bonding patterns were identified. The prepared compounds constitute active catalysts for the hydration of nitriles to amides under neutral conditions.
创建时间:
2007-04-23
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