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Anionic Iron Complexes with a Bond between an Ate-Type Pentacoordinated Germanium and an Iron Atom

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Anionic_Iron_Complexes_with_a_Bond_between_an_Ate_Type_Pentacoordinated_Germanium_and_an_Iron_Atom/2461837
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The first stable anionic iron(0) complexes bearing an ate-type pentacoordinated germanium­(IV) ligand were synthesized. The X-ray crystallographic analysis shows trigonal-bipyramidal and piano-stool geometries of germanium and iron, respectively. The complexes have moderately electron-rich iron centers and polar Ge–Fe bonds which can be cleaved by oxidation.
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2016-02-20
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